Synthesis and Reactivity of a Lewis?Base?Stabilized <i>tert</i> ?Butyl Arsanylborane: A Versatile Building Block for Arsenic?Boron Oligomers
نویسندگان
چکیده
The synthesis of the tert-butyl-substituted arsanylborane tBuAsHBH2 ? NMe3 is reported. Its reactivity towards main group Lewis acids and transition metal complexes, yielding various coordination products, discussed. Furthermore, it used as starting material in catenation oligomerization processes, leading to cationic catena compounds well neutral oligomers obtained by thermolysis.
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ژورنال
عنوان ژورنال: European Journal of Inorganic Chemistry
سال: 2021
ISSN: ['1434-1948', '1099-0682']
DOI: https://doi.org/10.1002/ejic.202100930